SYNTHESIS N-PHENYLAMINEDITHIOCARBAMATE AS CHELATING AGENT IN SOLVENT EXTRACTION

Abstract

Dithiocarbamate derivatives is a versatile ligand that contain two atoms of sulfur as a strong electron donor. It combines with metals. N-phenylaminedithiocarbamate has synthesized and applied in solvent exctration. Synthesis carried out with addition carbon disulphide to N-phenylamine and concentrated pottasium hydroxyde in metanol. The result was characterized by spectroscopy 1H-NMR, 13C-NMR, FTIR, Elemental Analysis, that showed molecular structure was significant. Applied N-Phenylaminedithiocarbamate in solvent extraction showed precent of result Cu(II), Co(II), Cr(III) and Ni (II) were 90.45% - 99.99% at pH 4-9.

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Volume

2

Issue

cna/vol2/iss3

Authors

Soja Siti Fatimah, Department of Education Chemistry, FPMIPA, UPIFollow
Vera Musfiroh
Zackiyah Zackiyah
Husein H. Bahti
Iwan Hastiawan
Anna Permanasari

Recommended Citation

Fatimah, Soja Siti; Musfiroh, Vera; Zackiyah, Zackiyah; Bahti, Husein H.; Hastiawan, Iwan; and Permanasari, Anna (2014) "SYNTHESIS N-PHENYLAMINEDITHIOCARBAMATE AS CHELATING AGENT IN SOLVENT EXTRACTION," Chimica et Natura Acta: Vol. 2: Iss. 3, Article 7.
DOI: https://doi.org/10.24198/cna.v2.n3.9160
Available at: https://journal.unpad.ac.id/cna/vol2/iss3/7